The summit of Armstrong, as well as Giant, are made of syenite gneiss, the rest of the High Peaks are made of metanorthosite. The reason for this difference is linked to the origin of the Adirondack Mountains themselves.
Much of the rock that we see in the High Peaks and the Adirondacks in general was formed about 1 billion years ago as the basement rock to a very large mountain range that would rival the size of the Himalayas. The rock we see today was miles below the surface, where it was metamorphisized. Over time these mountains eroded away and other geologic events happened, such as the European plate colliding with the North American plate. These events cracked the bedrock forming faults. These faults didn’t necessarily follow the arrangement of ridges and valleys of the ancient mountain range(s). The faults were then filled by magma forming igneous rocks. Much of this rock lay dormant while other geological events were happening, such as the formation of the Appalachian Mountains. Some time in the Tertiary Period (approximately 30million years ago) something caused and uplift (perhaps a hot spot) which pushed the bedrock towards the surface (this is still happening). Over time erosion; in particular glacial erosion, carved out the softer rock inside the faults leaving the harder metamorphic rock behind, which are the ranges we see today.
The different rock in Armstrong is because of the way the metamorphic rock was formed. A very weak argument could be made that Armstrong is not part of the Great Range because it doesn’t have the same geological makeup as the other mountains. But using the more general definition of mountain range, “is a group of mountains bordered by lowlands” (
http://www.answers.com/mountain+range&r=67) Armstrong is part of the same mountain range. One could also argue that Armstrong is part of the Great Range, because the same uplift and erosion patterns that formed the other mountains are the same that formed Armstrong as well. Using that same argument, Roostercomb, Snow, Hedgehog, Lower Wolfjaw, Upper Wolfjaw, Armstrong, Gothics, Sawteeth, Saddleback, Gooseberry, Basin, Haystack, Bartlett Ridge, Little Marcy, Marcy, Gray, Skylight, Redfield, Little Nippletop, McDonnel, and Allen would all be part of the Great Range, as there is no significant lowlands that separate the mountains.
I’m sure I missed a lot in my explanation and my regular hiking partner, who is a geologist, could explain it a lot better. This website is also helpful:
http://gretchen.geo.rpi.edu/roecker/nys/adir_txt.html